KRYLON PRODUCTS -- SPRAY PAINT AEROSOL, 1053 WINTER WHITE -- 8010-00N039229
===================== Product Identification ===================== Product ID:SPRAY PAINT AEROSOL, 1053 WINTER WHITE MSDS Date:06/23/1989 FSC:8010 NIIN:00N039229 === Responsible Party === Company Name:KRYLON PRODUCTS Address:180 EAST BROAD ST City:COLUMBUS State:OH ZIP:43215 Country:US Info Phone Num:614-431-6600;800-848-9400 Emergency Phone Num:614-431-6600 CAGE:IO479 === Contractor Identification === Company Name:BORDEN CHEMICAL CO Address:180 E BROAD ST Box:City:COLUMBUS State:OH ZIP:43215-3705 Country:US Phone:614-225-6124 CAGE:86142 Company Name:KRYLON PRODUCTS Address:180 EAST BROAD ST Box:City:COLUMBUS State:OH ZIP:43215 Country:US Phone:614-431-6600;800-848-9400 CAGE:IO479 ============= Composition/Information on Ingredients ============= Ingred Name:ING 17:ING 5:CAN CAUSE LIVER & KIDNEY DAMAGE. CAN CAUSE CNS DEPRESS. SIGNS/SYMPS MAY INCL HDCH, DIZZ, NAUS, (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18:VOMIT , UNCON & EVEN ASPHY. ING 6:CAN CAUSE CNS DEPRESS. SIGNS/SYMPS MAY INCL HDCH, DIZZ, NAUS, VOMIT & (ING 20) RTECS #:9999999ZZ Ingred Name:ING 19:DROWS. ING 7:CAN CAUSE LUNG FIBROSIS. NOTE:TOLUENE (CAS # 108-88-3) APPEARS ON THE NAVY LISTING OF (ING 21) RTECS #:9999999ZZ Ingred Name:ING 20:OCCUPATIONAL CHEMICAL REPRODUCTIVE HAZARDS. CONSULT WITH APPROPRIATE HEALTH PROFESSIONALS CONCERNING THE (ING 22) RTECS #:9999999ZZ Ingred Name:ING 21:LATEST HAZ LIST INFORMATION & SAFE HANDLING & USE RECOMMENDATIONS . EYE/SKIN:IRRIT. INGEST:BURNS (ING 23) RTECS #:9999999ZZ Ingred Name:ING 22:OR IRRIT TO MUC MEMB, ESOPHAGUS, OR GI TRACT. INHAL:LIQ OR VAP MAY CAUSE IRRIT OF NOSE, THROAT, & LUNGS. (ING 24) RTECS #:9999999ZZ Ingred Name:ING 23:CAN CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. RTECS #:9999999ZZ Ingred Name:OTHER PREC:FRESH AIR, WEAR NIOSH/MSHA APPRVD RESPIRATORY PROTECTION, OR LEAVE THE AREA. AVOID CONTACT WITH SKIN & EYES. RTECS #:9999999ZZ Ingred Name:2-BUTANONE;(METHYL ETHYL KETONE) (SARA III) CAS:78-93-3 RTECS #:EL6475000 Fraction by Wt: 30-50% OSHA PEL:200 PPM;300 STEL ACGIH TLV:200 PPM;300 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 5-10% OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:CYCLOHEXANONE (SARA III) CAS:108-94-1 RTECS #:GW1050000 Fraction by Wt: 1-5% OSHA PEL:S, 50 PPM ACGIH TLV:S, 25 PPM; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ACETIC ACID, ISOBUTYL ESTER;(ISOBUTYL ACETATE) (SARA III) CAS:110-19-0 RTECS #:AI4025000 Fraction by Wt: 10-30% OSHA PEL:150 PPM ACGIH TLV:150 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:TITANIUM OXIDE;(TITANIUM DIOXIDE) CAS:13463-67-7 RTECS #:XR2275000 Fraction by Wt: 1-5% OSHA PEL:15 MG/M3 TDUST ACGIH TLV:10 MG/M3 TDUST; 9293 Ingred Name:FIRST AID PROC:BE HELD APART DURING IRRIGATION TO INSURE WATER CONTACT W/ENTIRE SURFACE OF EYES/LIDS. CALL MD. RTECS #:9999999ZZ Ingred Name:VENT:SHOULD BE PROVIDED TO KEEP AIR CONTAM CONC LEVELS BELOW ACCEPTABLE CRITERIA. ENGINEERING CONTROLS:THE (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:FOLLOWING EXPOS CNTRL TECHNIQUES MAY BE USED TO EFFECTIVELY MIN EMPLOYEE EXPOS:LOC EXHST VENT, ENCLSD SYS (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:DESIGN, PROCESS ISOLATION & REMOTE CONTROL IN COMBINATION W/APPROP USE OF PERSONAL PROT EQUIP & PRUDENT (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:WORK PRACTICES. THESE TECH MAY NOT NEC ADDRESS ALL ISSUES PERTAINING TO YOUR OPERATIONS. WE, THEREFORE (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:REC THAT YOU CONSULT W/EXPERTS OF YOUR CHOICE TO DETERMINE WHETHER OR NOT YOUR PROGRAMS ARE ADEQUATE. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP:INTENTIONAL MISUSE BY DELIB CONC/INHALING CONTENTS MAY LEAD TO ADDICTION & MAY BE HARMFUL/FATAL.(ING 15) RTECS #:9999999ZZ Ingred Name:ING 14:ING 4:CAN CAUSE LIVER & KIDNEY DAMAGE. CAN CAUSE CNS DEPRESS. SIGNS/SYMPS MAY INCL HDCH, DIZZ, NAUS, (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15:VOMIT, UNCON & ASPHY. REPORTS HAVE ASSOC RPTD/PRLNGD OCCUP OVEREXP TO SOLVS W/PERM BRAIN & NERV SYS DMG (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16:INTENTIONAL MISUSE BY DELIB CONC & INHALING CONTENTS MAY LEAD TO ADDICTION & MAY BE HARMFUL/FATAL. (ING 18) RTECS #:9999999ZZ Ingred Name:PROPANE CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: 10-30% OSHA PEL:1000 PPM ACGIH TLV:SIMPLE ASPHYXIANT Ingred Name:PROPANE, 2-METHYL-;(ISOBUTANE) CAS:75-28-5 RTECS #:TZ4300000 Fraction by Wt: 10-30% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ING 1:MATL IS SIMPLE ASPHYXIANT. SIGNS/SYMPS OF OVEREXP MAY INCL CYANOSIS, RESP DISTRESS, HDCH, DIZZ, DROWS, UNCON & ASPHY. CAN CAUSE CNS DEPRESS. ING 3:SUSPECT REPROD HAZ. MAY CAUSE REPROD DISORDERS BASED ON ANIMAL DATA. METHYL ETHYL KETONE MAY POTENTIATE (SHORTEN TIME OF ONSET) PERIPHERAL NEUROPATHY(EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:CAUSED BY METHYL N-BUTYL KETONE OR N-HEXANE. METHYL ETHYL KETONE BY ITSELF HAS NOT BEEN SHOWN TO CAUSE PERIPHERAL NEUROPATHY. CAN CAUSE CNS DEPRESS. SIGNS/SYMPS MAY INCL HDCH, DIZZ, NAUS, VOM IT, UNCON & ASPHY. REPORTS HAVE ASSOC RPTD/PRLNGD OCCUPATIONAL OVEREXP TO SOLVS W/PERM BRAIN & NERV SYS DMG. (ING 14) Medical Cond Aggravated by Exposure:INGREDIENT 7:PRE-EXISTING RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE. ======================= First Aid Measures ======================= First Aid:INGEST:DILUTE BY DRINKING LRG QTYS OF WATER. IMMED CNTCT POIS CTL CTR OR HOSP EMERG ROOM FOR ANY OTHER ADDITIONAL TREATMENT DIRECTIONS. INHAL:MOVE TO FRESH AIR. IF NOT BRTHG GIVE ARTF RESP, PREF MOUTH TO MOUTH. SKIN:FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. REMOVE CONTAM CLTHG. CALL MD IF IRRIT PERSISTS. EYE:IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. EYELIDS SHOULD (ING 8) ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:SUPP DATA Extinguishing Media:DRY CHEMICAL, FOAM, OR CO*2. WATER MAY BE INEFFECTIVE BUT MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . AVOID HEAT. KEEP CONTAINER BELOW 120F. Unusual Fire/Explosion Hazard:HIGH TEMPS MAY CAUSE BURSTING. DO NOT PLACE CNTNR ON RADIATOR, STOVE, IN DIRECT SUNLIGHT OR NEAR OTHER HEAT SOURCES. DO NOT PUNCTURE CNTNR. CONTENTS (SUPP DATA) ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. SOAK UP WITH ABSORBENT MATERIAL AND REMOVE TO A CHEMICAL DISPOSAL AREA. PREVENT ENTRY INTO NATURAL BODIES OF WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:DO NOT STORE AT TEMPERATURES ABOVE 120F. KEEP AWAY FROM HEAT, SPARKS, FLAME AND OTHER IGNITION SOURCES. Other Precautions:USE WITH ADEQUATE VENTILATION. TO AVOID BREATHING VAPORS/SPRAY MIST, OPEN WINDOWS OR DOORS OR USE OTHER MEANS, SUCH AS AN EXHST FAN TO ENSURE FRESH AIR ENTRY DURING APPLIC & DRYING. IF YOU EXPERIENCE EYE WATERING, HDCH, DIZZ, INCR (ING 25) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE AIR CONTS CAN EXCEED ACCEPTABLE CRITERIA, USE NIOSH/MSHA APPROVED RESPIRATORY PROTECTION EQUIPMENT. RESPIRATORS SHOULD BE SELECTED BASED ON FORM & CONC OF CONTAMS IN AIR & I/A/W OSHA 29CFR1910.1 34 OR OTHER APPLIC STANDARDS/GUIDELINES. Ventilation:IF AIRBORNE CONTAMS ARE GENERATED WHEN MATL IS HEATED/HANDLED, SUFFICIENT VENT IN VOLUME & AIR FLOW PATTERNS (ING 9) Protective Gloves:IMPERVIOUS GLOVES. Eye Protection:CHEM WORK GOG W/FULL LNGTH FSHLD . Other Protective Equipment:SYNTHETIC APRON AND BOOTS IF CONTACT IS LIKELY. Work Hygienic Practices:HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICES. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health % VOLAT:96-98 (WT). FLASH PT:-156F, -104C (PROPELLANT); 23F, -5C (PAINT). EXPLO HAZ:UNDER PRESS WILL DISCHARGE. AVOID OPEN FLAMES, SPARKS, PILOT LIGHTS. DO NOT SMOKE. VAP MAY IGNITE EXPLO. SPRAY MIST/ VAP EVAP FROM DEPOSITED FILM IS HEAVIERTHAN AIR & MAY SETTLE IN LOW PLACES/TRAVEL OUTWARD TO IGNIT SOURCE & FLASH BACK. ================== Physical/Chemical Properties ================== Vapor Density:HVR/AIR Spec Gravity:LTR THAN H*2O Evaporation Rate & Reference:FASTER THAN BUTYL ACETATE Solubility in Water:SLIGHT Percent Volatiles by Volume:SUPDAT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS, ACIDS OR BASES. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:OXIDES OF CARBON. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF ACCORDING TO LOCAL, STATE, PROVINCIAL, AND FEDERAL REQUIREMENTS. EMPTY CONTAINER:MAY CONTAIN EXPLOSIVE VAPORS. DO NOT CUT, PUNCTURE OR WELD NEARBY. INCINERATION WILL CAUSE CONTAINER TO BURS T VIOLENTLY. 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