HERCULES CHEMICAL CO INC -- HERCULES PVC & CPVC PRIMER -- 8040-00F024672
===================== Product Identification ===================== Product ID:HERCULES PVC & CPVC PRIMER MSDS Date:03/27/1989 FSC:8040 NIIN:00F024672 === Responsible Party === Company Name:HERCULES CHEMICAL CO INC Address:84 5TH AVE City:NEW YORK State:NY ZIP:10011-7603 Country:US Info Phone Num:(212) 869-4330 Emergency Phone Num:(212) 869-4330 CAGE:84794 === Contractor Identification === Company Name:HERCULES CHEMICAL CO INC Address:111 SOUTH STREET(OLD IS 29 W 38 ST) Box:City:PASSAIC State:NJ ZIP:07055-7398 Country:US Phone:973-778-5000 CAGE:84794 ============= Composition/Information on Ingredients ============= Ingred Name:TETRAHYDROFURAN CAS:109-99-9 RTECS #:LU5950000 Other REC Limits:200 PPM OSHA PEL:200 PPM ACGIH TLV:590 MG/CUM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:2-BUTANONE (METHYL ETHYL KETONE) (MEK) CAS:78-93-3 RTECS #:EL6475000 Other REC Limits:590 MG/CUM OSHA PEL:200 PPM ACGIH TLV:590 MG/CUM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:CYCLOHEXANONE, KETOHEXAMETHYLENE CAS:108-94-1 RTECS #:GW1050000 Other REC Limits:100PPM (SKIN) STEL OSHA PEL:S, 50 PPM ACGIH TLV:S, 25 PPM; 9293 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EYES: CORROSIVE, IRRITATION, PAINFUL BURNING, STINGING, WATERING, INFLAMMATION OF CONJUNCTIVA. SKIN: IRRITATION, DERMATOSIS, SOLVENT DEFATTING. INHALATION: IRRITATION OF MUCOUS MEMBRANES/NOSE/EYES/THR OAT, COUGHING, DIFFICULTY BREATHING, HEADACHE, DIZZINESS, NAUSEA, & NARCOSIS. Explanation of Carcinogenicity:NONE Effects of Overexposure:EYES: CORROSIVE, IRRITATION, PAINFUL BURNING, STINGING, WATERING, INFLAMMATION OF CONJUNCTIVA. SKIN: IRRITATION, DERMATOSIS, SOLVENT DEFATTING. INHALATION: IRRITATION OF MUCOUS MEMBRANES/NOSE/THROAT/E YES, DIFFICULTY BREATHING, HEADACHE, DIZZINESS, NAUSEA, COUGHING, & NARCOSIS. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION, PREFERABLY MOUTH-TO-MOUTH. SKIN: WASH W/SOAP & WATER. EYES: FLUSH W/PLENTY OF WA TER FOR 15 MINS. INGESTION: DON'T INDUCE VOMITING. IF CONSCIOUS, DRINK TWO GLASSES OF WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:6F Lower Limits:2% Upper Limits:11.8% Extinguishing Media:FOAM, DRY CHEMICAL & CO2 Fire Fighting Procedures:USE SCBA & CHEMICAL GOGGLES. WATER MAY BE INEFFECTIVE, BUT CAN BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL. HANDLE AS FLAMMABLE LIQUID. Unusual Fire/Explosion Hazard:VAPORS ARE >AIR/TRAVEL CONSIDERABLE DISTANCE TO SOURCE OF IGNITION & FLASHBACK. ON LONG STANDING MAY FORM PEROXIDES WHICH CAN CAUSE VIOLENT REACTION. FLAMMABLE. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE IGNITION SOURCES. ABSORB W/SAND OR INERT ABSORBING MATERIAL & DISPOSE W/SOLID WASTE. FLUSH SPILL AREA W/WATER, AVOID FLUSHING INTO CONFINED AREAS. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, PLACE & WELL VENTILATED AREA. ELMINATE IGNITION SOURCES. AVOID CONTACT W/SKIN & EYES. Other Precautions:KEEP IN CLOSED CONTAINERS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED RESPIRATOR W/POSITIVE PRESSURE AIR-LINE MASK OR SELF-CONTAINED BREATHING APPARATUS IN CONFINED SPACES OR OTHER CIRCUMSTANCES WHERE ADEQUATE VENTILATION CANNOT BE ASSURED. Ventilation:LOCAL EXHAUST: AS REQUIRED. Protective Gloves:PVA Eye Protection:CHEMICAL SAFETY GOGGLES Other Protective Equipment:APRON, BOOTS, EYE BATH & SAFETY SHOWER Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. USE NORMAL GOOD PERSONAL HYGIENE. REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:151F Vapor Pres:70 Vapor Density:3 Spec Gravity:0.851 Evaporation Rate & Reference:(BU AC = 1): 5 Solubility in Water:54% Appearance and Odor:PURPLE LIQUID W/ETHEREAL & ACETONE LIKE ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING MATERIALS, LITHIUM ALUMINUM HYDRIDE, SODIUM ALUMINUM HYDROXIDE, SODIUM, POTASSIUM HYDROXIDES Stability Condition to Avoid:SPARKS, OPEN FLAME, & OTHER SOURCES OF IGNITION Hazardous Decomposition Products:CO, CO2, PEROXIDE FUMES Conditions to Avoid Polymerization:EXCESSIVE EXPOSURE TO AIR & CATONIC INITIATORS LIKE LEWIS ACIDS. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE IN COMPLIANCE W/LOCAL, STATE, & FEDERAL REGULATIONS. FLAMMABLE LIQUID. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.